Direct observation of structurally encoded metal discrimination and ether bond formation in a heterodinuclear metalloprotein
نویسندگان
چکیده
منابع مشابه
Direct observation of structurally encoded metal discrimination and ether bond formation in a heterodinuclear metalloprotein.
Although metallocofactors are ubiquitous in enzyme catalysis, how metal binding specificity arises remains poorly understood, especially in the case of metals with similar primary ligand preferences such as manganese and iron. The biochemical selection of manganese over iron presents a particularly intricate problem because manganese is generally present in cells at a lower concentration than i...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 2013
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.1304368110